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Alternate-stacked L...
Alternate-stacked Li4Ti5O12 nanosheets/d-Ti3C2 flexible film as a current collector-free, high-capacity and robust cathode for rechargeable Mg batteries
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- Yang, Chaoran (author)
- Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China.
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- Yang, Lanlan (author)
- Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China.
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- Chai, Zhigang (author)
- Uppsala universitet,Strukturkemi
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- Zheng, Xiang (author)
- Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China.
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- Li, Jianming (author)
- Res Inst Petr Explorat & Dev RIPED PetroChina, Beijing 100083, Peoples R China.
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- Yang, Yuying (author)
- Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China.
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- Zhu, Jiefang (author)
- Uppsala universitet,Strukturkemi
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- Jin, Xu (author)
- Res Inst Petr Explorat & Dev RIPED PetroChina, Beijing 100083, Peoples R China.
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- Li, Qi (author)
- Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China.
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- Xu, Dongsheng (author)
- Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China.
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Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China Strukturkemi (creator_code:org_t)
- 2020-06-28
- 2020
- English.
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In: Nano select. - : John Wiley & Sons. - 2688-4011. ; 1:1, s. 1-11
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Abstract
Subject headings
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- Rechargeable magnesium batteries (RMBs) have gained increasing attention owing to its high volumetric capacity, crust abundance, and safety from dendrite-free characteristic. However, the lack of development of high-performance cathode materials with long cycling stability and satisfactory capacity has greatly restricted the development of RMBs. Herein, a self-supported, current collector-free and soft electrode is prepared with delaminated Ti3C2 (d-Ti3C2) and Li4Ti5O12 nanosheets by simple vacuum filtration as flexible cathode in RMBs. Fabricated into a full cell with hybrid AlCl3/MgCl2/Mg(TFSI)2 electrolyte and Mg anode (a thin Mg foil with thickness of 50 μm), the flexible cathode shows high initial specific capacity of 320 mAh g−1 at 20 mA g−1, excellent cycling stability (good retention even after 1000 cycles) and outstanding rate performance. Detailed mechanistic studies reveal that introduction of d-Ti3C2 provide fast transport paths for electrons and Mg2+. The enlarged layer spacing of composited d-Ti3C2 accounts for significant increment in capacity. Benefiting from above-mentioned advantages, the best performance among Ti-based electrode materials is realized and make wearable devices powered by RMBs possible, thus circumventing the safety issues of lithium batteries.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Elektroteknik och elektronik -- Annan elektroteknik och elektronik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Electrical Engineering, Electronic Engineering, Information Engineering -- Other Electrical Engineering, Electronic Engineering, Information Engineering (hsv//eng)
Keyword
- 2D materials
- flexible electrodes
- long-term cycling
- Mg batteries
- MXenes
Publication and Content Type
- ref (subject category)
- art (subject category)
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To the university's database
- By the author/editor
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Yang, Chaoran
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Yang, Lanlan
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Chai, Zhigang
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Zheng, Xiang
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Li, Jianming
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Yang, Yuying
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show more...
-
Zhu, Jiefang
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Jin, Xu
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Li, Qi
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Xu, Dongsheng
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Materials Chemis ...
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- ENGINEERING AND TECHNOLOGY
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ENGINEERING AND ...
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and Electrical Engin ...
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and Other Electrical ...
- Articles in the publication
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Nano select
- By the university
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Uppsala University