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Syntheses of theaspirone and vitispirane via palladium(II)-catalyzed oxaspirocyclization
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- Nilsson, YIM (author)
- Uppsala universitet
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- Aranyos, A (author)
- Uppsala universitet
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- Andersson, PG (author)
- Uppsala universitet
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- (creator_code:org_t)
- AMER CHEMICAL SOC, 1996
- English 1825-1829 s.
- In: JOURNAL OF ORGANIC CHEMISTRY. - : AMER CHEMICAL SOC. ; 61:5
- Other publication (other academic/artistic)
Abstract
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- Total syntheses of theaspirone (A and B) and vitispirane (A and B) are described. The key step in the syntheses is the palladium(II)-catalyzed intramolecular oxaspirocyclization of diene alcohol 4 to either vitispirane or the allylic alcohol 9. The outco
Keyword
- STEREOCONTROLLED LACTONIZATION REACTIONS; PALLADIUM-CATALYZED 1;4-ADDITION; CONJUGATED DIENES; VOLATILE COMPONENTS; REDUCTION; CONSTITUENTS; NUCLEOPHILES; PRECURSORS; HYDRIDE; KETONES
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- vet (subject category)
- ovr (subject category)
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- Nilsson, YIM
- Aranyos, A
- Andersson, PG
- Backvall, JE
- Parrain, JL
- Ploteau, C
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- Quintard, JP
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