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Combining the [2,3]...
Combining the [2,3] sigmatropic rearrangement and ring-closing metathesis strategies for the synthesis of spirocyclic alkaloids. A short and efficient route to (+/-)-perhydrohistrionicotoxin.
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- Tanner, D (author)
- Uppsala universitet
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- Hagberg, L (author)
- Uppsala universitet
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- Poulsen, A (author)
- Uppsala universitet
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(creator_code:org_t)
- PERGAMON-ELSEVIER SCIENCE LTD, 1999
- English 1427-1440 s.
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In: TETRAHEDRON. - : PERGAMON-ELSEVIER SCIENCE LTD. ; 55:5
- Related links:
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https://urn.kb.se/re...
Abstract
Subject headings
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- This paper describes the use of selenium-based [2,3] sigmatropic rearrangement in combination with ruthenium-catalyzed ring-closing metathesis (RCM) for the synthesis of azaspiro ring systems, as exemplified by the reactions of model substrates 5 and 6.
Keyword
- rearrangements; metathesis; spiro compounds; alkaloids; MOLECULAR-FORCE FIELD; N-PHENYLSELENOPHTHALIMIDE; ORGANIC-SYNTHESIS; PHENYL SELENIDES; EPOTHILONE-A; MMFF94; GEOMETRIES; CATALYSTS; COMPONENT; ALCOHOLS
Publication and Content Type
- vet (subject category)
- ovr (subject category)
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