Search: onr:"swepub:oai:DiVA.org:uu-95087" >
A 3.0 mu s room tem...
A 3.0 mu s room temperature excited state lifetime of a bistridentate Ru-II-polypyridine complex for rod-like molecular arrays
-
- Abrahamsson, Maria (author)
- Uppsala universitet,Acceleratormasspektrometrigruppen,Institutionen för fotokemi och molekylärvetenskap
-
- Jäger, Michael (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
-
- Österman, Tomas (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap,Institutionen för kvantkemi
-
show more...
-
Eriksson, Lars (author)
-
- Persson, Petter (author)
- Uppsala universitet,Institutionen för kvantkemi
-
- Becker, Hans-Christian (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
-
- Johansson, Olof (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
-
- Hammarström, Leif (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
-
show less...
-
(creator_code:org_t)
- 2006-09-09
- 2006
- English.
-
In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 128:39, s. 12616-12617
- Related links:
-
https://urn.kb.se/re...
-
show more...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- A bistridentate RuII-polypyridine complex [Ru(bqp)2]2+ (bqp = 2,6-bis(8'-quinolinyl)pyridine) has been prepared, which has a coordination geometry much closer to a perfect octahedron than the typical Ru(terpyridine)2-type complex. Thus, the complex displays a 3.0 mus lifetime of the lowest excited metal-to-ligand charge transfer (3MLCT) state at room temperature. This is, to the best of our knowledge, the longest MLCT state lifetime reported for a RuII-polypyridyl complex at room temperature. The structure allows for the future construction of rod-like, isomer-free molecular arrays by substitution of donor and acceptor moieties on the central pyridine units. This makes it a promising photosensitizer for applications in molecular devices for artificial photosynthesis and molecular electronics.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database