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Family of Isoreticu...
Family of Isoreticular Chiral Metal-Organic Frameworks Based on Coordination and Hydrogen Bonds in [M[Co(ethylenediamine)(oxalato)2]2]
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- Borel, Cédric, 1979 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Davies, K. (author)
- University of Cape Town
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- HANDA, PAUL, 1980 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Hedberg, Gustav, 1982 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Oliver, C. L. (author)
- University of Cape Town
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- Bourne, S. A. (author)
- University of Cape Town
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- Håkansson, Mikael, 1957 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi,Department of Chemistry,University of Gothenburg
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- Langer, Vratislav, 1949 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Öhrström, Lars, 1963 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2010-02-26
- 2010
- English.
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In: Crystal Growth & Design. - : American Chemical Society (ACS). - 1528-7483 .- 1528-7505. ; 10:4, s. 1971-1978
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Abstract
Subject headings
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- From the parent compound [Ca[Co(ethylenediamine)(oxalato)2]2]n . 4H2O, 1, a series of framework compounds was prepared via the soluble sodium salt and crystal growth with the divalent metal ions Cd2+, Mn2+, and Sr2+, (2-4). These compounds have the same general formula [M[Co(ethylenediamine)(oxalato)2]2]n . xH2O, and they all form the same four- and eight-connected 3D net having scu topology (and are thus isoreticular) with water filled channels of variable size running in one direction of the crystals. However, they crystallize in two different space groups, the chiral P21) (3, 4, and the low temperature form of 1) and the noncentrosymmetric P-4 (1 and 2). The potential voids upon water removal are 18-20% of the unit cell. Preliminary gas sorption measurements at 298 K and 8 bar show substantial CO2 and N2O uptake (12-14% and 15-16% by mass, respectively), while the H2 uptake was 0.18%, a relatively high value considering the low pressure and high temperature.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Cambridge Structural Database
- Inorganic 3D Networks
- Crystal-Structure
- Thermal-Behavior
- 3-Periodic Nets
- Oxalates
- Polymers
- Chemistry
- Storage
- Solids
- Crystal-Structure
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Borel, Cédric, 1 ...
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Davies, K.
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HANDA, PAUL, 198 ...
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Hedberg, Gustav, ...
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Oliver, C. L.
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Bourne, S. A.
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Håkansson, Mikae ...
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Langer, Vratisla ...
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Öhrström, Lars, ...
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Inorganic Chemis ...
- Articles in the publication
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Crystal Growth & ...
- By the university
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University of Gothenburg
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Chalmers University of Technology