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Symmetry of [N-X-N]+ Halogen Bonds in Solution
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- Carlsson, Anna-Carin, 1976 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,Department of Chemistry and the Swedish NMR Centre, University of Gothenburg, Sweden
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- Gräfenstein, Jürgen, 1963 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,Department of Chemistry and the Swedish NMR Centre, University of Gothenburg, Sweden
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- Laurila, Jesse (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,Department of Chemistry and the Swedish NMR Centre, University of Gothenburg, Sweden
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- (creator_code:org_t)
- 2012
- 2012
- English.
- In: Chemical Communications. - 1364-548X .- 1359-7345. ; 48:10, s. 1458-1460
- Journal article (peer-reviewed)
Abstract
Subject headings
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- The first investigation of halogen bond symmetry is presented. In contrast to related hydrogen bonds, the iodous halogen bond is symmetric in solution and in the crystal. The bromous analogue is symmetric in solution, but shows asymmetry in the solid state. NMR results are in agreement with DFT predictions.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- halogen bonding
- NMR
Publication and Content Type
- ref (subject category)
- art (subject category)
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