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New efficient ligand for sub-mol % copper-catalyzed C-N cross-coupling reactions running under air
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- Larsson, Per-Fredrik, 1983 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
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- Astvik, Peter (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
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- Norrby, Per-Ola, 1962 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
- (creator_code:org_t)
- 2012-11-09
- 2012
- English.
- In: Beilstein Journal of Organic Chemistry. - : Beilstein Institut. - 1860-5397. ; 8, s. 1909-1915
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- A new efficient ligand, N,N ''-dimethyldiethylene triamine (DMDETA), has been synthesized and evaluated for sub-mol % copper-catalyzed C-N cross-coupling reactions. The efficiency of the ligand was determined by kinetic methods. DMDETA proved to display efficiency similar to DMEDA and, in addition, the resulting catalyst was tolerant to air.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- copper
- cross coupling
- hyperactivity
- kinetics
- ligands
- aryl halides
- o-arylation
- room-temperature
- vinyl halides
- diaryl
- ethers
- bond formation
- amino-acid
- arylboronic acids
- highly efficient
- mild conditions
- nney db
- 1980
- journal of the american chemical society
- v102
- p7072
Publication and Content Type
- ref (subject category)
- art (subject category)
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