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Total Synthesis of ...
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Ekebergh, Andreas,1984Chalmers tekniska högskola,Chalmers University of Technology
(author)
Total Synthesis of Nostodione A, a Cyanobacterial Metabolite
- Article/chapterEnglish2012
Publisher, publication year, extent ...
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2012-12-10
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American Chemical Society (ACS),2012
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electronicrdacarrier
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LIBRIS-ID:oai:gup.ub.gu.se/170412
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https://gup.ub.gu.se/publication/170412URI
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https://doi.org/10.1021/ol303036jDOI
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https://research.chalmers.se/publication/170412URI
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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The first total synthesis of the mitotic spindle poison nostodione A is described. The inherent oxidative sensitivity of indoles is utilized for a late introduction of a second carbonyl to the cyclopent[b]indole-2-one system. The tricyclic system is prepared from indole-3-acetic acid and O-silylated 4-ethynylphenol, using a stereoselective intramolecular reductive Heck cyclization as the key transformation.
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Börje, Anna,1961Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,University of Gothenburg(Swepub:gu)xboann
(author)
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Mårtensson, Jerker,1965Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)jerker
(author)
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Chalmers tekniska högskolaInstitutionen för kemi och molekylärbiologi
(creator_code:org_t)
Related titles
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In:Organic Letters: American Chemical Society (ACS)14:24, s. 6274-62771523-70601523-7052
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