onr:"swepub:oai:gup.ub.gu.se/335230"
Search: onr:"swepub:oai:gup.ub.gu.se/335230" > A Bi-based artifici...
- 1 of 1
- Previous record
- Next record
- To hitlist
A Bi-based artificial interphase to achieve ultra-long cycling life of Al-metal anode in non-aqueous electrolyte
- Kumar, Sonal (author)
-
- Rama, Prasad (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
- Lieu, Wei Ying (author)
- show more...
- Zhang, Chang (author)
- Busayaporn, Wutthikrai (author)
- Chinnadurai, Deviprasath (author)
- Yang, Gaoliang (author)
- Xing, Zhenxiang (author)
- Li, Yuanjian (author)
- Liu, Wei (author)
- Seh, Zhi Wei (author)
- show less...
- (creator_code:org_t)
- 2024
- 2024
- English.
- In: Energy Storage Materials. - 2405-8297. ; 65
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- Rechargeable aluminum-ion batteries (RAB) with Al-metal anode are regarded as cost-effective and environmentally sustainable energy storage systems. However, tapping the high volumetric capacity of the Al-anode has been a challenge because of the spontaneous and irreversible formation of the oxide layer on its surface that renders it electrochemically inactive. Though recently reported AlCl3-based electrolytes overcome this problem by breaking down this oxide layer, their highly corrosive nature hampers commercialization. Here, we investigate a novel approach to protect the Al-anode from severe oxidation by engineering an artificial protective interphase. A unique and less corrosive combination of Al(CF3SO3)3 salt and BiCl3 additive reacts with the Al-anode intrinsically to form an inorganic-rich protective bilayer. This layer is electronically insulating and significantly reduces the charge transfer resistance and surface activation energy at the anode, enabling plating/stripping at extremely low overpotential of <0.1 V that can be sustained for record-long cycling times of >4000 h.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- Al-ion batteries
- Anodic overpotential
- Multivalent batteries
- Solid electrolyte interface
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- Energy Storage Materials (Search for host publication in LIBRIS)
To the university's database
- 1 of 1
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Kumar, Sonal
- Rama, Prasad
- Lieu, Wei Ying
- Zhang, Chang
- Busayaporn, Wutt ...
- Chinnadurai, Dev ...
- show more...
- Yang, Gaoliang
- Xing, Zhenxiang
- Li, Yuanjian
- Abbas, Zareen, 1 ...
- Liu, Wei
- Seh, Zhi Wei
- show less...
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- and Materials Chemis ...
- Articles in the publication
- Energy Storage M ...
- By the university
- University of Gothenburg
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
