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Isotope effects in dynamics of water isotopologues induced by core ionization at an x-ray free-electron laser

Guillemin, R. (author)
Paris-Sorbonne University
Inhester, L. (author)
German Electron Synchrotron (DESY)
Ilchen, M. (author)
German Electron Synchrotron (DESY),European XFEL GmbH
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Mazza, T. (author)
European XFEL GmbH
Boll, R. (author)
European XFEL GmbH
Weber, Th. (author)
Lawrence Berkeley National Laboratory
Eckart, S. (author)
Goethe University
Grychtol, P. (author)
European XFEL GmbH
Rennhack, N. (author)
European XFEL GmbH
Marchenko, T. (author)
Paris-Sorbonne University
Velasquez, N. (author)
Paris-Sorbonne University
Travnikova, O. (author)
Paris-Sorbonne University
Ismail, I. (author)
Paris-Sorbonne University
Niskanen, J. (author)
University of Turku
Kukk, E. (author)
University of Turku
Trinter, F. (author)
German Electron Synchrotron (DESY),Fritz Haber Institute of the Max Planck Society
Gisselbrecht, M. (author)
Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,LTH profilområde: Avancerade ljuskällor,LTH profilområden,LU profilområde: Ljus och material,Lunds universitets profilområden,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,LTH Profile Area: Photon Science and Technology,LTH Profile areas,Faculty of Engineering, LTH,LU Profile Area: Light and Materials,Lund University Profile areas
Feifel, Raimund (author)
University of Gothenburg,Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)
Sansone, G. (author)
Albert-Ludwigs University Freiburg
Rolles, D. (author)
Kansas State University
Martins, M. (author)
University of Hamburg,European XFEL GmbH,The French National Centre for Scientific Research (CNRS),Paris-Sorbonne University
Meyer, M. (author)
Simon, M. (author)
Santra, R. (author)
German Electron Synchrotron (DESY),University of Hamburg
Pfeifer, T. (author)
Max Planck Institute for Nuclear Physics
Jahnke, T. (author)
Max Planck Institute for Nuclear Physics
Piancastelli, M. N. (author)
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 (creator_code:org_t)
2023
2023
English.
In: STRUCTURAL DYNAMICS-US. - 2329-7778. ; 10:5
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Dynamical response of water exposed to x-rays is of utmost importance in a wealth of science areas. We exposed isolated water isotopologues to short x-ray pulses from a free-electron laser and detected momenta of all produced ions in coincidence. By combining experimental results and theoretical modeling, we identify significant structural dynamics with characteristic isotope effects in H2O2+, D2O2+, and HDO2+, such as asymmetric bond elongation and bond-angle opening, leading to two-body or three-body fragmentation on a timescale of a few femtoseconds. A method to disentangle the sequences of events taking place upon the consecutive absorption of two x-ray photons is described. The obtained deep look into structural properties and dynamics of dissociating water isotopologues provides essential insights into the underlying mechanisms.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

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