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Axial motion of wat...
Axial motion of water hydrogen halide and water halogen complexes in argon matrices
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- Engdahl, Anders (author)
- Lund University,Lunds universitet,Naturvetenskapliga fakulteten,Faculty of Science
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- Nelander, Bengt (author)
- Lund University,Lunds universitet,Naturvetenskapliga fakulteten,Faculty of Science
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(creator_code:org_t)
- AIP Publishing, 1986
- 1986
- English 7 s.
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In: The Journal of chemical physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 84:4, s. 1981-1987
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http://dx.doi.org/10...
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Abstract
Subject headings
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- The infrared spectra of the water (H2O, HDO, D2O) complexes with HCl, HBr, HI Cl2, Br2, and I2 have been studied in argon matrices in the 11 to 25 K interval. In all cases, water acts as a lone-pair donor. The hydrogen halide complexes are effectively planar and rotate around the axis through the heavy atoms. For the water halogen complexes, the results are less clear, but a similar rotation, coupled to low wave number bending motions, seems possible.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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