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Spin-state studies ...
Spin-state studies with XES and RIXS: From static to ultrafast
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Vanko, Gyoergy (author)
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Bordage, Amelie (author)
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Glatzel, Pieter (author)
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Gallo, Erik (author)
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Rovezzi, Mauro (author)
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Gawelda, Wojciech (author)
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Galler, Andreas (author)
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Bressler, Christian (author)
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Doumy, Gilles (author)
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March, Anne Marie (author)
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Kanter, Elliot P. (author)
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Young, Linda (author)
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Southworth, Stephen H. (author)
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- Canton, Sophie (author)
- Lund University,Lunds universitet,MAX IV-laboratoriet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,MAX IV Laboratory,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Uhlig, Jens (author)
- Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Smolentsev, Grigory (author)
- Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Sundström, Villy (author)
- Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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Haldrup, Kristoffer (author)
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van Driel, Tim Brandt (author)
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Nielsen, Martin M. (author)
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Kjaer, Kasper S. (author)
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Lemke, Henrik T. (author)
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(creator_code:org_t)
- Elsevier BV, 2013
- 2013
- English.
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In: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048. ; 188, s. 166-171
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Abstract
Subject headings
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- We report on extending hard X-ray emission spectroscopy (XES) along with resonant inelastic X-ray scattering (RIXS) to study ultrafast phenomena in a pump-probe scheme at MHz repetition rates. The investigated systems include low-spin (LS) Fe-II complex compounds, where optical pulses induce a spin-state transition to their (sub)nanosecond-lived high-spin (HS) state. Time-resolved XES clearly reflects the spin-state variations with very high signal-to-noise ratio, in agreement with HS-LS difference spectra measured at thermal spin crossover, and reference HS-LS systems in static experiments, next to multiplet calculations. The 1s2p RIXS, measured at the Fe Is pre-edge region, shows variations after laser excitation, which are consistent with the formation of the HS state. Our results demonstrate that X-ray spectroscopy experiments with overall rather weak signals, such as RIXS, can now be reliably exploited to study chemical and physical transformations on ultrafast time scales. (C) 2012 Elsevier B.V. All rights reserved.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Keyword
- Molecular switching
- Time-resolved spectroscopy
- X-ray spectroscopy
- Spin transition
- Photoinduced transition
- Ultrafast phenomena
- Pump-probe experiments
Publication and Content Type
- art (subject category)
- ref (subject category)
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- By the author/editor
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Vanko, Gyoergy
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Bordage, Amelie
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Glatzel, Pieter
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Gallo, Erik
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Rovezzi, Mauro
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Gawelda, Wojciec ...
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show more...
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Galler, Andreas
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Bressler, Christ ...
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Doumy, Gilles
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March, Anne Mari ...
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Kanter, Elliot P ...
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Young, Linda
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Southworth, Step ...
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Canton, Sophie
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Uhlig, Jens
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Smolentsev, Grig ...
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Sundström, Villy
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Haldrup, Kristof ...
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van Driel, Tim B ...
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Nielsen, Martin ...
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Kjaer, Kasper S.
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Lemke, Henrik T.
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Atom and Molecul ...
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Journal of Elect ...
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Lund University