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Carbon-hydrogen bon...
Carbon-hydrogen bond activation of phenyldi(2-thienyl)phosphine at a triosmium cluster centre
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Ghosh, Shishir (author)
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Hogarth, Graeme (author)
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Tocher, Derek A. (author)
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- Nordlander, Ebbe (author)
- Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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Kabir, Shariff E. (author)
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(creator_code:org_t)
- Elsevier BV, 2010
- 2010
- English.
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In: Inorganica Chimica Acta. - : Elsevier BV. - 0020-1693. ; 363:7, s. 1611-1614
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http://dx.doi.org/10...
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Abstract
Subject headings
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- The phenyldi(2-thienyl)phosphine (PhPTh2) complexes [Os-3(CO)(12-n)(PhPTh2)(n)] (n = 1-3) (1-3) have been prepared. Thermolysis of 1 and either 2 or 3 in octane affords carbon-hydrogen bond activation products [Os-3(CO)(9){mu(3)-PPhTh(C4H2S)}(mu-H)] (4) and [Os-3(CO)(8)(PPhTh2){mu(3)-PPhTh(C4H2S)}(mu-H)] (5), respectively. Both exist as isomeric mixtures differing in the relative positions of phenyl and thienyl substituents with respect to the triosmium centre. The nature of the process has been confirmed by a single crystal X-ray diffraction analysis of 4. (C) 2010 Elsevier B.V. All rights reserved.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Keyword
- activation
- Carbon-hydrogen bond
- Triosmium clusters
- Phenyldi(2-thienyl)phosphine
- X-ray structures
Publication and Content Type
- art (subject category)
- ref (subject category)
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