Degradation of Ge subcells by thermal load during the growth of multijunction solar cells

• Germanium solar cells are used as bottom subcells in many multijunction solar cell designs. The question remains whether the thermal load originated by the growth of the upper layers of the multijunction solar cell structure affects the Ge subcell performance. Here, we report and analyze the performance degradation of the Ge subcell due to such thermal load in lattice-matched GaInP/Ga(In)As/Ge triple-junction solar cells. Specifically, we have detected a quantum efficiency loss in the wavelength region corresponding to the emitter layer (which accounts for up to 20% loss in equivalent JSC) and up to 55 mV loss in VOC of the Ge subcell as compared with analogous devices grown as single-junction Ge solar cells on the same type of substrates. We prove experimentally that there is no direct correlation between the loss in VOC and the doping level of the base. Our simulations show that both the JSC and VOC losses are consistent with a degradation of the minority carrier properties at the emitter, in particular at the initial nanometers of the emitter next to the emitter/window heterointerface. In addition, we also rule out the gradual emitter profile shape as the origin of the degradation observed. Our findings underscore the potential to obtain higher efficiencies in Ge-based multijunction solar cells if strategies to mitigate the impact of the thermal load are taken into consideration.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Naturresursteknik -- Energisystem (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Environmental Engineering -- Energy Systems (hsv//eng)

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

Keyword

Ge solar cells

multijunction solar cells

thermal degradation

thermal load

EU Horizon 2020

NEXTNANOCELLS

Grant 656208

Publication and Content Type

art (subject category)

ref (subject category)