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- Engdahl, AndersLund University,Lunds universitet,Naturvetenskapliga fakulteten,Faculty of Science (author)
On the relative stabilities of H- And D-bonded water dimers
- Article/chapterEnglish1987
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- AIP Publishing,1987
- 5 s.
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- LIBRIS-ID:oai:lup.lub.lu.se:3b113612-b964-4c22-9f83-74141be4fe1b
- https://lup.lub.lu.se/record/3b113612-b964-4c22-9f83-74141be4fe1bURI
- https://doi.org/10.1063/1.452182DOI
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- Language:English
- Summary in:English
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- The infrared spectra of water dimers formed from H2O, D 2O, and HDO in krypton matrices have been recorded. Thermal equilibria between H- and D-bonded dimers have been studied. D bonding is preferred, and H-bonded dimers are approximately 60 cm-1 less stable than D-bonded dimers. The energy difference seems to be due to the higher value of the intermolecular out-of-plane H-bond shear vibration compared to the corresponding D-bond vibration.
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- Nelander, BengtLund University,Lunds universitet,Naturvetenskapliga fakulteten,Faculty of Science(Swepub:lu)chph-bne (author)
- Lunds universitetNaturvetenskapliga fakulteten (creator_code:org_t)
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- In:The Journal of chemical physics: AIP Publishing86:4, s. 1819-18230021-96061089-7690
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