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Spherical Micelles ...
Spherical Micelles with Nonspherical Cores : Effect of Chain Packing on the Micellar Shape
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- König, Nico (author)
- Jülich Research Centre,University of Oslo
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- Willner, Lutz (author)
- Jülich Research Centre
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- Carlström, Göran (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Zinn, Thomas (author)
- European Synchrotron Radiation Facility
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- Knudsen, Kenneth D. (author)
- Institute for Energy Technology
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- Rise, Frode (author)
- University of Oslo
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- Topgaard, Daniel (author)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Lund, Reidar (author)
- University of Oslo
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(creator_code:org_t)
- 2020-11-18
- 2020
- English.
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In: Macromolecules. - : American Chemical Society (ACS). - 0024-9297 .- 1520-5835. ; , s. 10686-10698
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Abstract
Subject headings
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- Self-assembly of amphiphilic polymers into micelles is an archetypical example of a "self-confined"system due to the formation of micellar cores with dimensions of a few nanometers. In this work, we investigate the chain packing and resulting shape of Cn-PEOx micelles with semicrystalline cores using small/wide-angle X-ray scattering (SAXS/WAXS), contrast-variation small-angle neutron scattering (SANS), and nuclear magnetic resonance spectroscopy (NMR). Interestingly, the n-alkyl chains adopt a rotator-like conformation and pack into prolate ellipses (axial ratio ϵ ≈ 0.5) in the "crystalline"region and abruptly arrange into a more spheroidal shape (ϵ ≈ 0.7) above the melting point. We attribute the distorted spherical shape above the melting point to thermal fluctuations and intrinsic rigidity of the n-alkyl blocks. We also find evidence for a thin dehydrated PEO layer (≤1 nm) close to the micellar core. The results provide substantial insight into the interplay between crystallinity and molecular packing in confinement and the resulting overall micellar shape.
Subject headings
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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