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Ultrafast charge tr...
Ultrafast charge transfer and atomic orbital polarization
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Deppe, M. (author)
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Foehlisch, A. (author)
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- Hennies, Franz (author)
- Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory
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Sanchez-Portal, D. (author)
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Echenique, P. M. (author)
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Wurth, W. (author)
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(creator_code:org_t)
- AIP Publishing, 2007
- 2007
- English.
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In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 127:17
- Related links:
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http://dx.doi.org/10...
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The role of orbital polarization for ultrafast charge transfer between an atomic adsorbate and a substrate is explored. Core hole clock spectroscopy with linearly polarized x-ray radiation allows to selectively excite adsorbate resonance states with defined spatial orientation relative to the substrate surface. For c(4x2)S/Ru(0001) the charge transfer times between the sulfur 2s(-1)3p(*+1) antibonding resonance and the ruthenium substrate have been studied, with the 2s electron excited into the 3p(perpendicular to)(*) state along the surface normal and the 3p(parallel to)(*) state in the surface plane. The charge transfer times are determined as 0.18 +/- 0.07 and 0.84 +/- 0.23 fs, respectively. This variation is the direct consequence of the different adsorbate-substrate orbital overlap.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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