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Synthesis of Substituted Benzo[b]indolizidines and Benzo[b]quinolizidines via Ring-Opening of 3-Bromo-2,5-dimethylthiophene-1,1-dioxide
- Tsirk, Anders (author)
-
- Gronowitz, Salo (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Hörnfeldt, Anna-Britta (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
- (creator_code:org_t)
- 1997
- 1997
- English.
- In: Tetrahedron. - 0040-4020. ; 53:2, s. 771-784
- Journal article (peer-reviewed)
Abstract
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- A new method for the preparation of benzo[b]indolizidines and benzo[b]quinolizidines based on two reactions: an amine induced ring-opening of 3-bromo-2,5-dimethylthiophene-1,1-dioxide (1) with 2-allyl-pyrrolidine (2), 2-allylpiperidine (3), 2-[2-(1',3'-dithiolan)methyl]pyrrolidine (4) and 2-[2-(1'-3'-dithiolan)methyl]piperidine (5); and an intramolecular Diels-Alder reaction, is described. Copyright (C) 1996 Elsevier Science Ltd
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
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