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Electronic ground s...
Electronic ground state of Ni 2 +
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- Zamudio-Bayer, V. (author)
- Helmholtz Association of German Research Centers,Albert-Ludwigs University Freiburg
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- Lindblad, R. (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Helmholtz Association of German Research Centers
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- Bülow, C. (author)
- Helmholtz Association of German Research Centers
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- Leistner, G. (author)
- Helmholtz Association of German Research Centers
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- Terasaki, A. (author)
- Toyota Technological Institute
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- Issendorff, B. V. (author)
- Albert-Ludwigs University Freiburg
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- Lau, J. T. (author)
- Helmholtz Association of German Research Centers
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(creator_code:org_t)
- AIP Publishing, 2016
- 2016
- English.
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In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 145:19
- Related links:
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http://dx.doi.org/10...
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Abstract
Subject headings
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- The Φ9/24 ground state of the Ni2+ diatomic molecular cation is determined experimentally from temperature and magnetic-field-dependent x-ray magnetic circular dichroism spectroscopy in a cryogenic ion trap, where an electronic and rotational temperature of 7.4±0.2 K was reached by buffer gas cooling of the molecular ion. The contribution of the spin dipole operator to the x-ray magnetic circular dichroism spin sum rule amounts to 7Tz=0.17±0.06μB per atom, approximately 11% of the spin magnetic moment. We find that, in general, homonuclear diatomic molecular cations of 3d transition metals seem to adopt maximum spin magnetic moments in their electronic ground states.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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