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A boot-strap Poisson-Boltzmann theory for the structure and thermodynamics of chargd colloidal solutions
- Petris, S N (author)
- Chan, D Y C (author)
-
- Linse, Per (author)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
- (creator_code:org_t)
- AIP Publishing, 2003
- 2003
- English.
- In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 118:11, s. 5248-5259
- Journal article (peer-reviewed)
Abstract
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- The structural properties and thermodynamics of one- and two-component solutions of charged colloidal particles with explicit counterions have been investigated by Monte Carlo simulation. A boot-strap Poisson-Boltzmann (BSPB) theory has been developed to interpret these results and the accuracy of its predictions is compared with other existing theories. The BSPB was also used to predict the gas-liquid binodal and spinodal curves for a one-component system with colloid charge to counterion-charge ratio Z(r)=10. (C) 2003 American Institute of Physics.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
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- ref (subject category)
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