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Chain End-Functiona...
Chain End-Functionalized Polymer Brushes with Switchable Fluorescence Response
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- Tas, Sinem (author)
- University of Twente
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- Kopec´, Maciej (author)
- University of Twente
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- van der Pol, Rianne (author)
- University of Twente
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- Cirelli, Marco (author)
- University of Twente
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- de Vries, Ilse (author)
- University of Twente
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- Bölükbas, Deniz A. (author)
- Lund University,Lunds universitet,Lungbioengineering och regeneration,Forskargrupper vid Lunds universitet,Lung Bioengineering and Regeneration,Lund University Research Groups
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- Tempelman, Kristianne (author)
- University of Twente
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- Benes, Nieck E. (author)
- University of Twente
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- Hempenius, Mark A. (author)
- University of Twente
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- Vancso, G. Julius (author)
- University of Twente
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- de Beer, Sissi (author)
- University of Twente
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(creator_code:org_t)
- 2019-01-03
- 2019
- English.
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In: Macromolecular Chemistry and Physics. - : Wiley. - 1022-1352. ; 220:5
- Related links:
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http://dx.doi.org/10...
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https://ris.utwente....
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Herein is described the switchable fluorescence response of poly(methyl methacrylate) (PMMA) brushes. Chain end fluorescein labeled PMMA brushes are prepared by combining surface-initiated atom transfer radical polymerization (SI-ATRP) with a copper-catalyzed alkyne-azide cycloaddition (CuAAC) click reaction. Successful attachment of fluorescein is confirmed by measuring fluorescence of the as-prepared films. Utilizing co-solvency of PMMA in isopropanol-water mixtures, responsive behavior of the end-functionalized brushes is demonstrated by measuring the changes in fluorescence intensity between the swollen and collapsed states.
Subject headings
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Keyword
- co-solvency
- fluorescent polymers
- polymer brushes
- solvent responsiveness
Publication and Content Type
- art (subject category)
- ref (subject category)
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- By the author/editor
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Tas, Sinem
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Kopec´, Maciej
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van der Pol, Ria ...
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Cirelli, Marco
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de Vries, Ilse
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Bölükbas, Deniz ...
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show more...
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Tempelman, Krist ...
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Benes, Nieck E.
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Hempenius, Mark ...
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Vancso, G. Juliu ...
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de Beer, Sissi
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Polymer Chemistr ...
- Articles in the publication
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Macromolecular C ...
- By the university
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Lund University