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Access to the Bis-b...
Access to the Bis-benzene Cobalt(I) Sandwich Cation and its Derivatives : Synthons for a “Naked” Cobalt(I) Source?
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- Meier, Stefan C. (author)
- Albert-Ludwigs University Freiburg
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- Holz, Albina (author)
- Albert-Ludwigs University Freiburg
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- Kulenkampff, Jan (author)
- Albert-Ludwigs University Freiburg
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- Schmidt, Alexei (author)
- Albert-Ludwigs University Freiburg
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- Kratzert, Daniel (author)
- Albert-Ludwigs University Freiburg
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- Himmel, Daniel (author)
- Albert-Ludwigs University Freiburg
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- Schmitz, Dominik (author)
- University of Augsburg
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- Scheidt, Ernst Wilhelm (author)
- University of Augsburg
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- Scherer, Wolfgang (author)
- University of Augsburg
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- Bülow, Christine (author)
- Technical University of Berlin
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- Timm, Martin (author)
- Technical University of Berlin
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- Lindblad, Rebecka (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Helmholtz Association of German Research Centers
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- Akin, Scott T. (author)
- University of Georgia
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- Zamudio-Bayer, Vicente (author)
- Albert-Ludwigs University Freiburg
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- von Issendorff, Bernd (author)
- Albert-Ludwigs University Freiburg
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- Duncan, Michael A. (author)
- University of Georgia
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- Lau, J. Tobias (author)
- Albert-Ludwigs University Freiburg
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- Krossing, Ingo (author)
- Albert-Ludwigs University Freiburg
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(creator_code:org_t)
- 2018-06-25
- 2018
- English 5 s.
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In: Angewandte Chemie - International Edition. - : Wiley. - 1433-7851. ; 57:30, s. 9310-9314
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http://dx.doi.org/10...
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https://lup.lub.lu.s...
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Abstract
Subject headings
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- The synthesis and structural characterization of the hitherto unknown parent Co(bz)2 + (bz=benzene) complex and several of its derivatives are described. Their synthesis starts either from a CoCO5 + salt, or directly from Co2(CO)8 and a Ag+ salt. Stability and solubility of these complexes was achieved by using the weakly coordinating anions (WCAs) [Al(ORF)4]− and [F{Al(ORF)3}2]− {RF=C(CF3)3} and the solvent ortho-difluorobenzene (o-DFB). The magnetic properties of Co(bz)2 + were measured and compared in the condensed and gas phases. The weakly bound Co(o-dfb)2 + salts are of particular interest for the preparation of further CoI salts, for example, the structurally characterized low-coordinate 12 valence electron Co(PtBu3)2 + and Co(NHC)2 + salts.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- arene ligands
- cobalt
- magnetic properties
- sandwich complexes
- weakly coordinating anion
Publication and Content Type
- art (subject category)
- ref (subject category)
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To the university's database
- By the author/editor
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Meier, Stefan C.
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Holz, Albina
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Kulenkampff, Jan
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Schmidt, Alexei
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Kratzert, Daniel
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Himmel, Daniel
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show more...
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Schmitz, Dominik
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Scheidt, Ernst W ...
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Scherer, Wolfgan ...
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Bülow, Christine
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Timm, Martin
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Lindblad, Rebeck ...
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Akin, Scott T.
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Zamudio-Bayer, V ...
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von Issendorff, ...
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Duncan, Michael ...
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Lau, J. Tobias
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Krossing, Ingo
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
- Articles in the publication
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Angewandte Chemi ...
- By the university
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Lund University