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On the Transformation Mechanism of K2Ti4O9 to TiO2(B) and Formation of Microvoids

Wallenberg, Reine (author)
Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
Sanati, Mehri (author)
Lund University,Lunds universitet,Ergonomi och aerosolteknologi,Institutionen för designvetenskaper,Institutioner vid LTH,Lunds Tekniska Högskola,Ergonomics and Aerosol Technology,Department of Design Sciences,Departments at LTH,Faculty of Engineering, LTH
Andersson, Arne (author)
Lund University,Lunds universitet,Avdelningen för kemiteknik,Institutionen för processteknik och tillämpad biovetenskap,Institutioner vid LTH,Lunds Tekniska Högskola,Division of Chemical Engineering,Department of Process and Life Science Engineering,Departments at LTH,Faculty of Engineering, LTH
 (creator_code:org_t)
EDP Sciences, 1990
1990
English.
In: Microscopy Microanalysis Microstructures. - : EDP Sciences. - 1154-2799. ; 1:5-6, s. 357-364
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • TiO2(B), a potential catalyst support, has been synthesized from a support precursor, K2Ti4O9. High resolution electron microscopy revealed that the 32% volume loss in this transformation is achieved by formation of facetted microvoids, around 10 nm in size, maintaining the morphology and size of the original crystals. A structural mechanism, including a hypothetical structure for a K2Ti 2O5 intermediate, is suggested.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Maskinteknik -- Produktionsteknik, arbetsvetenskap och ergonomi (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Mechanical Engineering -- Production Engineering, Human Work Science and Ergonomics (hsv//eng)
TEKNIK OCH TEKNOLOGIER  -- Kemiteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Chemical Engineering (hsv//eng)
NATURVETENSKAP  -- Kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

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