Search: onr:"swepub:oai:lup.lub.lu.se:6f1e49ca-47db-463b-bdfc-af236de3980c" >
Effects of Sr/Ti-ra...
Effects of Sr/Ti-ratio in SrTiO3-based SOFC anodes investigated by the use of cone-shaped electrodes
-
- Blennow Tullmar, Peter (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
Kammer Hansen, Kent (author)
-
- Wallenberg, Reine (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
show more...
-
Mogensen, Mogens (author)
-
show less...
-
(creator_code:org_t)
- Elsevier BV, 2006
- 2006
- English.
-
In: Electrochimica Acta. - : Elsevier BV. - 0013-4686. ; 52:4, s. 1651-1661
- Related links:
-
http://dx.doi.org/10... (free)
-
show more...
-
https://lup.lub.lu.s...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- In this work the A-site deficiency limit for undoped SrTiO3, calcined in air or reducing atmosphere, was investigated. XRD and SEM analyses showed that when using the solid-state synthesis route it was difficult to achieve any A-site deficiency. Even very small deviations from unity in the Sr/Ti-ratio resulted in impurity phases. The effects of Sr/Ti-ratio on the performance of SrTiO3 anodes for solid oxide fuel cells (SOFCs) was investigated by impedance spectroscopy with cone-shaped electrodes. The electrocatalytic activity of the SrTiO3 cone samples, with various amount of reduced titanium dioxide phases (Magnéli phases), was investigated for oxidation of H2 at 700 °C. High temperature treatment at 1000 °C, between the measurements at 700 °C, showed that high content of Magnéli phases leads to faster degradation of the activity. The suitability for using cone-shaped electrodes as a tool for investigating electrode materials is discussed.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Magnéli phases
- Area normalization
- A-site deficiency
- Cone-shaped electrode
- SrTiO3
Publication and Content Type
- art (subject category)
- ref (subject category)
Find in a library
To the university's database