Search: onr:"swepub:oai:lup.lub.lu.se:cb0d92b8-6feb-4833-918f-4b154e51c9d7" > Ultrafast Jahn-Tell...
Fältnamn | Indikatorer | Metadata |
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000 | 04989naa a2200529 4500 | |
001 | oai:lup.lub.lu.se:cb0d92b8-6feb-4833-918f-4b154e51c9d7 | |
003 | SwePub | |
008 | 230925s2023 | |||||||||||000 ||eng| | |
024 | 7 | a https://lup.lub.lu.se/record/cb0d92b8-6feb-4833-918f-4b154e51c9d72 URI |
024 | 7 | a https://doi.org/10.1002/advs.2022068802 DOI |
040 | a (SwePub)lu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a art2 swepub-publicationtype |
072 | 7 | a ref2 swepub-contenttype |
100 | 1 | a Canton, Sophie E.u European XFEL GmbH,Technical University of Denmark4 aut |
245 | 1 0 | a Ultrafast Jahn-Teller Photoswitching in Cobalt Single-Ion Magnets |
264 | 1 | c 2023 |
520 | a Single-ion magnets (SIMs) constitute the ultimate size limit in the quest for miniaturizing magnetic materials. Several bottlenecks currently hindering breakthroughs in quantum information and communication technologies could be alleviated by new generations of SIMs displaying multifunctionality. Here, ultrafast optical absorption spectroscopy and X-ray emission spectroscopy are employed to track the photoinduced spin-state switching of the prototypical complex [Co(terpy)2]2+ (terpy = 2,2′:6′,2″-terpyridine) in solution phase. The combined measurements and their analysis supported by density functional theory (DFT), time-dependent-DFT (TD-DFT) and multireference quantum chemistry calculations reveal that the complex undergoes a spin-state transition from a tetragonally elongated doublet state to a tetragonally compressed quartet state on the femtosecond timescale, i.e., it sustains ultrafast Jahn-Teller (JT) photoswitching between two different spin multiplicities. Adding new Co-based complexes as possible contenders in the search for JT photoswitching SIMs will greatly widen the possibilities for implementing magnetic multifunctionality and eventually controlling ultrafast magnetization with optical photons. | |
650 | 7 | a NATURVETENSKAPx Fysikx Den kondenserade materiens fysik0 (SwePub)103042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciencesx Condensed Matter Physics0 (SwePub)103042 hsv//eng |
653 | a Jahn-Teller effect | |
653 | a photoswitching | |
653 | a single-ion-magnets | |
653 | a XFEL science | |
700 | 1 | a Biednov, Mykolau European XFEL GmbH4 aut |
700 | 1 | a Pápai, Mátyásu Wigner Research Centre for Physics, Hungarian Academy of Sciences,Technical University of Denmark4 aut |
700 | 1 | a Lima, Frederico A.u European XFEL GmbH4 aut |
700 | 1 | a Choi, Tae Kyuu European XFEL GmbH,Pohang University of Science and Technology4 aut |
700 | 1 | a Otte, Florianu European XFEL GmbH4 aut |
700 | 1 | a Jiang, Yifengu European XFEL GmbH4 aut |
700 | 1 | a Frankenberger, Paulu European XFEL GmbH4 aut |
700 | 1 | a Knoll, Martinu European XFEL GmbH4 aut |
700 | 1 | a Zalden, Peteru European XFEL GmbH4 aut |
700 | 1 | a Gawelda, Wojciechu Adam Mickiewicz University in Poznań,IMDEA Nanociencia,Autonomous University of Madrid,European XFEL GmbH4 aut |
700 | 1 | a Rahaman, Ahiburu Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,Technical University of Denmark4 aut0 (Swepub:lu)chem-arm |
700 | 1 | a Møller, Klaus B.u Technical University of Denmark4 aut |
700 | 1 | a Milne, Christopheru European XFEL GmbH4 aut |
700 | 1 | a Gosztola, David J.u Argonne National Laboratory4 aut |
700 | 1 | a Zheng, Kaibou Lund University,Lunds universitet,NanoLund: Centre for Nanoscience,Annan verksamhet, LTH,Lunds Tekniska Högskola,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,LTH profilområde: Nanovetenskap och halvledarteknologi,LTH profilområden,LTH profilområde: Avancerade ljuskällor,LU profilområde: Ljus och material,Lunds universitets profilområden,Other operations, LTH,Faculty of Engineering, LTH,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,LTH Profile Area: Nanoscience and Semiconductor Technology,LTH Profile areas,Faculty of Engineering, LTH,LTH Profile Area: Photon Science and Technology,Faculty of Engineering, LTH,LU Profile Area: Light and Materials,Lund University Profile areas,Technical University of Denmark4 aut0 (Swepub:lu)chem-kbz |
700 | 1 | a Retegan, Mariusu European Synchrotron Radiation Facility4 aut |
700 | 1 | a Khakhulin, Dmitryu European XFEL GmbH4 aut |
710 | 2 | a European XFEL GmbHb Technical University of Denmark4 org |
773 | 0 | t Advanced Scienceg 10:21q 10:21x 2198-3844 |
856 | 4 | u http://dx.doi.org/10.1002/advs.202206880x freey FULLTEXT |
856 | 4 8 | u https://lup.lub.lu.se/record/cb0d92b8-6feb-4833-918f-4b154e51c9d7 |
856 | 4 8 | u https://doi.org/10.1002/advs.202206880 |
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