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Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters
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- Elding, Lars Ivar (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Nordlander, Ebbe (author)
- Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Kiriakidou, Keranio (author)
- University of Bologna
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- (creator_code:org_t)
- Royal Society of Chemistry (RSC), 1998
- 1998
- English 2 s.
- In: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1364-548X .- 1359-7345. ; 1998:24, s. 2721-2722
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Osmium carbonyls
- Cluster complex
- Addition Reactions
- Kinetics
- Reaction mechanism
Publication and Content Type
- art (subject category)
- ref (subject category)
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- Johansson, Maria
- Valls, Esteve
- Gobetto, Roberto
- Aime, Silvio
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