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Nonadiabatic effect...
Nonadiabatic effects in photoelectron spectra of HCl and DCl. I. Experiment
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- Burmeister, F (author)
- Uppsala University
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- Ristinmaa Sörensen, Stacey (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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- Bjorneholm, O (author)
- Uppsala University
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de Brito, AN (author)
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- Fink, RF (author)
- Uppsala University
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- Feifel, R (author)
- Uppsala University
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- Hjelte, I (author)
- Uppsala University
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- Wiesner, K (author)
- Uppsala University
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- Giertz, A (author)
- Uppsala University
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- Bässler, M (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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- Miron, C (author)
- Uppsala University
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- Wang, H (author)
- Lund University
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- Piancastelli, MN (author)
- University of Rome Tor Vergata
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- Karlsson, L (author)
- Uppsala University
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- Svensson, S (author)
- Uppsala University
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(creator_code:org_t)
- 2002
- 2002
- English.
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In: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 65:1
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Abstract
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- The HCl inner-valence photoelectron band at 26 eV binding energy has been recorded at high resolution. Discrete peaks arising from at least two separate vibrational progressions are superimposed on the broad continuum. Fano profiles are visible in one of the progressions. This indicates interference between superimposed electronic states, where weak avoided crossing allows two adiabatic states to couple. In the isotopic DCl molecular spectrum, the discrete lines are less pronounced, due to slower dissociation and therefore less coupling between the continuum and the bound state.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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- By the author/editor
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Burmeister, F
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Ristinmaa Sörens ...
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Bjorneholm, O
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de Brito, AN
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Fink, RF
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Feifel, R
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show more...
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Hjelte, I
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Wiesner, K
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Giertz, A
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Bässler, M
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Miron, C
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Wang, H
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Piancastelli, MN
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Karlsson, L
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Svensson, S
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Atom and Molecul ...
- Articles in the publication
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Physical Review ...
- By the university
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Lund University