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Probing RbBr solvation in freestanding sub-2 nm water clusters

Hautala, Lauri (author)
University of Oulu
Jänkälä, Kari (author)
University of Oulu
Mikkelä, Mikko Heikki (author)
Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory
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Turunen, Paavo (author)
University of Oulu
Prisle, Nønne L. (author)
University of Oulu
Patanen, Minna (author)
University of Oulu
Tchaplyguine, Maxim (author)
Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory
Huttula, Marko (author)
University of Oulu
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 (creator_code:org_t)
2017
2017
English 10 s.
In: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9076 .- 1463-9084. ; 19:36, s. 25158-25167
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Concentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg-1. For comparison, spectra from anhydrous RbBr clusters are also presented.

Subject headings

NATURVETENSKAP  -- Kemi -- Fysikalisk kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Physical Chemistry (hsv//eng)

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