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The water dimer in a too tight matrix cage
- Engdahl, Anders (author)
-
- Nelander, Bengt (author)
- Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
- (creator_code:org_t)
- 2002-04-23
- 2002
- English.
- In: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9084 .- 1463-9076. ; 4:11, s. 2140-2143
- Journal article (peer-reviewed)
Abstract
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- When an argon matrix containing hydrogen peroxide dimer is irradiated with 266 nm radiation from a YAG laser, water forms. Some of it is formed as monomer but the main part is formed as dimer. The photogenerated water dimer is formed together with an oxygen molecule in the cage of the parent hydrogen peroxide dimer and the dimer bands are shifted from their normal positions indicating that the cage severely perturbs the product structure.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
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