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Emission decay kine...
Emission decay kinetics in a CaWO4 : Bi crystal
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Nagirnyi, V (author)
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Kotlov, A (author)
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- Jönsson, Leif (author)
- Lund University,Lunds universitet,Partikel- och kärnfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Particle and nuclear physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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Kirm, M (author)
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Lushchik, A (author)
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(creator_code:org_t)
- Elsevier BV, 2005
- 2005
- English.
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In: Nuclear Instruments & Methods in Physics Research. Section A: Accelerators, Spectrometers, Detectors, and Associated Equipment. - : Elsevier BV. - 0167-5087 .- 0168-9002. ; 537:1-2, s. 61-65
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Abstract
Subject headings
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- The decay kinetics of the 2.88 eV emission of pure and Bi-doped CaWO4 crystals has been studied in the temperature region of 4.2-300 K. The decay components connected with the radiative transitions from the triplet excited states of regular WO42- oxyanionic complexes and WO42- complexes perturbed by Bi3+ ions (WO42-(Bi3+) centres) have been identified. It is shown that WO4(Bi3+) centres can be excited directly above the edge of the fundamental absorption of CaWO4, or due to the energy transfer from the metastable state of a Bi3+ ion at the excitation in the Bi3+ absorption band at 4.4e.V. At temperatures T> 170 K, the excited state of the WO42-(Bi3+) centre is thermally ionised, giving rise to phosphorescence in the blue spectral region. These processes are compared with those known for excitons in PbWO4 crystals.
Subject headings
- NATURVETENSKAP -- Fysik -- Acceleratorfysik och instrumentering (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Accelerator Physics and Instrumentation (hsv//eng)
Keyword
- emission decay kinetics
- triplet states
- CaWO4 : Bi
- energy transfer
Publication and Content Type
- art (subject category)
- ref (subject category)
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