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  • Muthu, D. V SUniversity of Missouri-Kansas City (author)

Pressure-induced phase transitions in α-ZrMo2O8

  • Article/chapterEnglish2002

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  • 2002
  • 5 s.

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  • LIBRIS-ID:oai:lup.lub.lu.se:fb3bcacf-6974-4b14-8490-e6720457ee2c
  • https://lup.lub.lu.se/record/fb3bcacf-6974-4b14-8490-e6720457ee2cURI

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  • Language:English
  • Summary in:English

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  • Subject category:art swepub-publicationtype
  • Subject category:ref swepub-contenttype

Notes

  • We report high-pressure Raman, infrared (IR), and optical-absorption spectra of α-ZrMo2O8 (trigonal) up to 38 GPa at room temperature. The spectroscopic studies are consistent with diffraction results that show that α-ZrMo2O8 transforms into δ-ZrMo2O8 (monoclinic) at about 1 GPa and the δ phase converts to the ε phase (triclinic) at about 2.0 GPa. Optical-absorption measurements give an estimate of the band gap of about 0.6 eV at the lowest pressure. Band-gap changes with pressure are confirmed with visual observations. ZrMo2O8 changes from transparent at 5 GPa to yellow at 10 GPa, red at 18 GPa, and at about 30 GPa it becomes opaque.

Added entries (persons, corporate bodies, meetings, titles ...)

  • Chen, B.University of Missouri-Kansas City (author)
  • Wrobel, J. M.University of Missouri-Kansas City (author)
  • Andersen, A. M KroghUniversity of Missouri-Kansas City (author)
  • Carlson, S.Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory(Swepub:lu)inor-sca (author)
  • Kruger, M. B.University of Missouri-Kansas City (author)
  • University of Missouri-Kansas CityMAX IV-laboratoriet (creator_code:org_t)

Related titles

  • In:Physical Review B (Condensed Matter)65:6, s. 641011-6410150163-1829

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