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Kinetic study of the selective reduction of nitric oxide over vanadia—tungsta—titania/sepiolite catalyst
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- Odenbrand, Ingemar (author)
- Lund University,Lunds universitet,Avdelningen för kemiteknik,Institutionen för processteknik och tillämpad biovetenskap,Institutioner vid LTH,Lunds Tekniska Högskola,Division of Chemical Engineering,Department of Process and Life Science Engineering,Departments at LTH,Faculty of Engineering, LTH
- Bahamonde, A (author)
- Avila, P (author)
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- Blanco, J (author)
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- (creator_code:org_t)
- 1994
- 1994
- English.
- In: Applied Catalysis B: Environmental. - 0926-3373. ; 5:1-2, s. 117-131
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- A kinetic study of the reduction of nitric oxide by ammonia in the presence of oxygen on a novel catalyst prepared as a physical mixture of V2O5-WO3/TiO2 catalyst and a natural silicate (sepiolite) was carried out. The steady-state differential reactor data were fitted to several equations using a discriminating method based on physical and statistic criteria. The best fit was obtained from a model involving adsorption of ammonia and oxygen which react with nitric oxide from the gas phase following an Eley-Rideal mechanism. The equation considered for this model reproduces well the experimental results obtained in a differential regime. Important limitations by internal diffusion were determined when the reaction took place in an integral regime.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering (hsv//eng)
Keyword
- AMMONIA
- KINETICS
- NITRIC OXIDE REDUCTION
- SELECTIVE CATALYTIC
- REDUCTION
- SEPIOLITE
- TITANIA
- TUNGSTA
- VANADIA
Publication and Content Type
- art (subject category)
- ref (subject category)
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