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Li-O-2 Battery Degr...
Li-O-2 Battery Degradation by Lithium Peroxide (Li2O2): A Model Study
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- Younesi, Reza (author)
- Uppsala universitet,Strukturkemi
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- Hahlin, Maria (author)
- Uppsala universitet,Strukturkemi
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- Björefors, Fredrik (author)
- Uppsala universitet,Strukturkemi
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- Johansson, Patrik, 1969 (author)
- Chalmers tekniska högskola,Chalmers University of Technology,Department of Applied Physics, Chalmers University of Technology
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- Edström, Kristina, 1958- (author)
- Uppsala universitet,Strukturkemi
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(creator_code:org_t)
- 2012-12-18
- 2013
- English.
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In: Chemistry of Materials. - : American Chemical Society (ACS). - 1520-5002 .- 0897-4756. ; 25:1, s. 77-84
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http://dx.doi.org/10...
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Abstract
Subject headings
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- The chemical stability of the Li-O-2 battery components (cathode and electrolyte) in contact with lithium peroxide (Li2O2) was investigated using X-ray photoelectron spectroscopy (XPS). XPS is a versatile method to detect amorphous as well as crystalline decomposition products of both salts and solvents. Two strategies were employed. First, cathodes including carbon, alpha-MnO2 catalyst, and Kynar binder (PVdF-HFP) were exposed to Li2O2 and LiClO4 in propylene carbonate (PC) or tetraethylene glycol dimethyl ether (TEGDME) electrolytes. The results indicated that Li2O2 degrades TEGDME to carboxylate containing species and that the decomposition products, in turn, degraded the Kynar binder. The alpha-MnO2 catalyst was unaffected. Second, Li2O2 model surfaces were kept in contact with different electrolytes to investigate the chemical stability and also the resulting surface layer on Li2O2. Further, the XPS experiments revealed that the Li salts such as LiPF6, LiBF4, and LiC!
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Materialteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- chemistry
- li-air batteries
- oxygen battery
- XPS
- carbonate electrolytes
- electrochemistry
- lithium-air battery
- chemical decomposition
- ether
- X-ray photoelectron spectroscopy
- Li2O2
- lithium peroxide
- lithium oxygen
- electrodes
- ray photoelectron-spectroscopy
- reactivity
- stability
- Inorganic chemistry
- Chemistry with specialization in Polymer Chemistry
- Chemistry with specialization in Materials Chemistry
Publication and Content Type
- art (subject category)
- ref (subject category)
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