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Poly(methimazolyl)b...
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Abernethy, R. J.
(author)
Poly(methimazolyl)borato nitrosyl complexes of molybdenum and tungsten
- Article/chapterEnglish2008
Publisher, publication year, extent ...
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2008-08-14
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American Chemical Society (ACS),2008
Numbers
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LIBRIS-ID:oai:research.chalmers.se:2a42aab9-62c3-40d1-b28f-c0b806503774
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https://research.chalmers.se/publication/167263URI
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https://doi.org/10.1021/om800416jDOI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:art swepub-publicationtype
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Subject category:ref swepub-contenttype
Notes
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The syntheses of a range of poly(methimazolyl)borate -ligated nitrosyl complexes of tungsten and molybdenum are reported, the characterization of which includes the crystal structure determinations of the compounds [W(NO)(CO)(2){k(3)-S,S',S''-HB(mt)(3)}], [W(NO)(CO)(2)(PPh3){k(2)-S,S'-H2B(mt)(2)}], and [Mo(NO-)(CO)(2) {k(3)-H,S,S'-H2B(mt)(2)}] (mt = methimazoyl). The reaction of [W(NO)(CO)(3)(PPh3)(2)]PF6 with Na[HB(mt)(3)] and Na[H2B(mt)(2)}] provides respectively [W(NO)(CO)(2)[HB(mt)(3)] and [W(NO)(CO)(2)(PPh3){k(2_) S,S'-H2B(mt)(2)}]. The complexes [M(NO)(CO)(2){HB(mt)(3)}] and [M(NO)(CO)(2){k(3)-H,S,S'-H2B(mt)(2)}] (M = W, Mo) arise from the reactions of Na[M(CO)(3){H2B(mt)(2)}] with N-methyl-N-nitrosotoluenesulfonamide. The molybdenum complex [Mo(NO)(CO)(2){HB(mt)(3)}] is also obtained unexpectedly from the reaction of [MO(eta(3)-C3H5)(CO)(2){HB(mt)(3)}] with [NO]BF4.
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Foreman, Mark,1973Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)foreman
(author)
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Hill, A. F.
(author)
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Tshabang, N.
(author)
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Willis, A. C.
(author)
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Young, R. D.
(author)
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Chalmers tekniska högskola
(creator_code:org_t)
Related titles
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In:Organometallics: American Chemical Society (ACS)27:17, s. 4455-44630276-73331520-6041
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