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Oxidation of Fe-10Cr in O-2 and in O-2+H2O environment at 600 degrees C: A microstructural investigation

Jonsson, Torbjörn, 1970 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Pujilaksono, Bagas, 1965 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Heidari, H. (author)
Chalmers tekniska högskola,Chalmers University of Technology
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Liu, Fang, 1975 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Svensson, Jan-Erik, 1965 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Halvarsson, Mats, 1965 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Johansson, Lars-Gunnar, 1952 (author)
Chalmers tekniska högskola,Chalmers University of Technology
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 (creator_code:org_t)
Elsevier BV, 2013
2013
English.
In: Corrosion Science. - : Elsevier BV. - 0010-938X. ; 75, s. 326-336
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Oxidation of Fe-10Cr in dry and wet O-2 was studied at 600 degrees C for up to 168 h. Oxide microstructure was investigated by STEM/EDX, FIB/SEM and TEM. Oxidation in dry O-2 gives a Cr-rich protective (Fe1-xCrx)(2)O-3 scale. The same protective oxide initially forms in O-2 + H2O environment, but after an incubation period scale breakdown is triggered by CrO2(OH)(2) evaporation that depletes the substrate in Cr and converts (Fe1-xCrx)(2)O-3 to FeCr spinel oxide. Internal oxidation occurs after breakaway. Alternating external and internal oxidation result in the inward-growing scale showing a characteristic banded morphology.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Materialteknik -- Metallurgi och metalliska material (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Materials Engineering -- Metallurgy and Metallic Materials (hsv//eng)

Keyword

TEM
Internal oxidation
STEM
Stainless steel
High temperature corrosion

Publication and Content Type

art (subject category)
ref (subject category)

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