Adsorption and reactions of O2 and D2 on small free palladium clusters in a cluster-molecule scattering experiment

• The adsorption of oxygen and hydrogen (deuterium) on small neutral palladium clusters was investigated in a cluster beam experiment. The beam passes through two low-pressure reaction cells, and the clusters, with and without adsorbed molecules, are detected using laser ionization and mass spectrometry. Both H2 and O2 adsorb efficiently on the palladium clusters with only moderate variations with cluster size in the investigated range, i.e. between 8 and 28 atoms. The co-adsorption of H2 and O2 results in the formation of H2O, detected as a decrease in the number of adsorbed oxygen atoms with an increasing number of collisions with H2 molecules. A comparison is done with an earlier similar study of clusters of Pt. Furthermore a comparison is done with what is known for sticking and reactivity of surfaces.

Subject headings

NATURVETENSKAP  -- Kemi -- Fysikalisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Physical Chemistry (hsv//eng)

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Keyword

surface reaction

palladium

cluster

molecular beam

Publication and Content Type

art (subject category)

ref (subject category)