Search: onr:"swepub:oai:research.chalmers.se:5c829996-5ed6-41ee-a23c-44cf6cf696b8" >
Impact of Sulfur-Co...
Impact of Sulfur-Containing Additives on Lithium-Ion Battery Performance: From Computational Predictions to Full-Cell Assessments
-
- Jankowski, Piotr, 1990 (author)
- Centre national de la recherche scientifique (CNRS),Politechnika Warszawska,Warsaw University of Technology,Chalmers tekniska högskola,Chalmers University of Technology
-
- Lindahl, Niklas, 1981 (author)
- Chalmers tekniska högskola,Chalmers University of Technology,Chalmers University of Technology, Sweden
-
- Weidow, Jonathan, 1980 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
-
show more...
-
- Wieczorek, W. (author)
- Centre national de la recherche scientifique (CNRS),Politechnika Warszawska,Warsaw University of Technology
-
- Johansson, Patrik, 1969 (author)
- Chalmers tekniska högskola,Chalmers University of Technology,Centre national de la recherche scientifique (CNRS)
-
show less...
-
(creator_code:org_t)
- 2018-05-29
- 2018
- English.
-
In: ACS Applied Energy Materials. - : American Chemical Society (ACS). - 2574-0962. ; 1, s. 2582-2591
- Related links:
-
https://research.cha...
-
show more...
-
https://research.cha...
-
https://doi.org/10.1...
-
https://research.cha...
-
https://urn.kb.se/re...
-
show less...
Abstract
Subject headings
Close
- Electrolyte additives are pivotal for stabilization of lithium-ion batteries, by suppressing capacity loss through creation of an engineered solid-electrolyte-interphase-layer (SEI-layer) at the negative electrode and thereby increasing lifetime. Here, we compare four different sulfur-containing 5-membered-ring molecules as SEI-formers: 1,3,2-dioxathiolane-2,2-dioxide (DTD), propane-1,3-sultone (PS), sulfopropionic acid anhydride (SPA), and prop-1-ene-1,3-sultone (PES). Density functional theory calculations and electrochemical measurements both confirm appropriate reduction potentials. For a connection of the protective properties of the SEIs formed to the chemical structure of the additives, the decomposition paths are computed and compared with spectroscopic data for the negative electrode surface. The performance of full-cells cycled using a commercial electrolyte and the different additives reveals the formation of organic dianions to play a crucial beneficial role, more so for DTD and SPA than for PS and PES.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Maskinteknik -- Energiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Mechanical Engineering -- Energy Engineering (hsv//eng)
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Naturresursteknik -- Energisystem (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Environmental Engineering -- Energy Systems (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
Keyword
- DFT
- solid electrolyte interphase
- additives
- sulfur-containing compounds
- battery cycling
- Li-ion battery
Publication and Content Type
- art (subject category)
- ref (subject category)
Find in a library
To the university's database