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Mass spectrometry of alditols as trimethylsilyl derivatives

Petersson, Göran, 1941 (author)
Chalmers tekniska högskola,Chalmers University of Technology
 (creator_code:org_t)
1969
1969
English.
In: Tetrahedron. ; 25, s. 4437-4443
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Trimethylsilyl ethers of alditols with 3, 4, 5 and 6 C atoms were investigated. The mass spectra are unusually clearly correlated with the structures. The predominant fragmentations are cleavages in the carbon chain and rearrangement loss of trimethylsilanol. The spectra are closely related to those of the methyl ethers. A spectrum unambiguously identifies a compound as an alditol and permits the determination of its molecular weight.

Subject headings

NATURVETENSKAP  -- Kemi -- Analytisk kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Analytical Chemistry (hsv//eng)

Keyword

Me3Si derivatives
sugar alcohols
xylitol
separation
identification

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art (subject category)
ref (subject category)

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