Search: onr:"swepub:oai:research.chalmers.se:74ea798c-7b32-4db5-83b4-72f830dc043a" >
Selective Iron-Medi...
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Dunås, Petter,1990Chalmers tekniska högskola,Chalmers University of Technology
(author)
Selective Iron-Mediated C- and O-Addition of Phenolic Nucleophiles to a Cyclohexadiene Scaffold Using Renewable Precursors
- Article/chapterEnglish2019
Publisher, publication year, extent ...
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2019-02-28
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American Chemical Society (ACS),2019
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electronicrdacarrier
Numbers
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LIBRIS-ID:oai:research.chalmers.se:74ea798c-7b32-4db5-83b4-72f830dc043a
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https://doi.org/10.1021/acssuschemeng.9b00127DOI
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https://research.chalmers.se/publication/509365URI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:art swepub-publicationtype
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Subject category:ref swepub-contenttype
Notes
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Renewable phenols have been investigated as nucleophiles for the addition to a cationic cyclohexadienyl iron carbonyl scaffold. Benign conditions compatible with solvents such as ethanol and water were developed, and for the first time, selective C- or O-addition could be achieved. In addition, a novel atom-economic approach to forming the C-addition products directly from the neutral precursor complex in a single step using a catalytic acid is described. The formed C-addition product could then be selectively demetalated to form one of two different product classes, a functionalized arene or a cyclohexadiene.
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Paterson, Andrew,1988Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)andrewp
(author)
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Kociok-Köhn, G.University of Bath
(author)
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Lewis, Simon E.University of Bath
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Kann, Nina,1964Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)kann
(author)
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Chalmers tekniska högskolaUniversity of Bath
(creator_code:org_t)
Related titles
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In:ACS Sustainable Chemistry & Engineering: American Chemical Society (ACS)7:7, s. 7155-71622168-0485
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