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- Dunås, Petter,1990Chalmers tekniska högskola,Chalmers University of Technology (author)
Selective Iron-Mediated C- and O-Addition of Phenolic Nucleophiles to a Cyclohexadiene Scaffold Using Renewable Precursors
- Article/chapterEnglish2019
Publisher, publication year, extent ...
- 2019-02-28
- American Chemical Society (ACS),2019
- electronicrdacarrier
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- LIBRIS-ID:oai:research.chalmers.se:74ea798c-7b32-4db5-83b4-72f830dc043a
- https://doi.org/10.1021/acssuschemeng.9b00127DOI
- https://research.chalmers.se/publication/509365URI
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- Language:English
- Summary in:English
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Notes
- Renewable phenols have been investigated as nucleophiles for the addition to a cationic cyclohexadienyl iron carbonyl scaffold. Benign conditions compatible with solvents such as ethanol and water were developed, and for the first time, selective C- or O-addition could be achieved. In addition, a novel atom-economic approach to forming the C-addition products directly from the neutral precursor complex in a single step using a catalytic acid is described. The formed C-addition product could then be selectively demetalated to form one of two different product classes, a functionalized arene or a cyclohexadiene.
Subject headings and genre
- TEKNIK OCH TEKNOLOGIER Kemiteknik Kemiska processer hsv//swe
- ENGINEERING AND TECHNOLOGY Chemical Engineering Chemical Process Engineering hsv//eng
- TEKNIK OCH TEKNOLOGIER Industriell bioteknik Biokatalys och enzymteknik hsv//swe
- ENGINEERING AND TECHNOLOGY Industrial Biotechnology Biocatalysis and Enzyme Technology hsv//eng
- NATURVETENSKAP Kemi Organisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Organic Chemistry hsv//eng
- Water
- Iron
- Renewable resources
- Cyclohexadiene
- Metal carbonyl
- Green chemistry
- Phenols
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- Paterson, Andrew,1988Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)andrewp (author)
- Kociok-Köhn, G.University of Bath (author)
- Lewis, Simon E.University of Bath (author)
- Kann, Nina,1964Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)kann (author)
- Chalmers tekniska högskolaUniversity of Bath (creator_code:org_t)
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- In:ACS Sustainable Chemistry & Engineering: American Chemical Society (ACS)7:7, s. 7155-71622168-0485
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