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A Novel Li+-Nafion-...
A Novel Li+-Nafion-Sulfonated Graphene Oxide Membrane as Single Lithium-Ion Conducting Polymer Electrolyte for Lithium Batteries
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- Nicotera, Isabella (author)
- Università della Calabria,University of Calabria
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- Simari, Cataldo (author)
- Università della Calabria,University of Calabria
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- Agostini, Marco, 1987 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Enotiadis, Apostolos (author)
- University of Ioannina
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- Brutti, Sergio (author)
- Universita degli Studi di Roma la Sapienza,Sapienza University of Rome
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(creator_code:org_t)
- 2019-10-31
- 2019
- English.
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In: Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 123:45, s. 27406-27416
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https://doi.org/10.1...
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Abstract
Subject headings
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- Single lithium-ion conducting polymer electrolytes are an innovative concept of solid-state polymer electrolytes (SPEs) for lithium-battery technology. In this work, a lithiated Nafion nanocomposite incorporating sulfonated graphene oxide (sGO-Li+), as well as a filler-free membrane, have been synthesized and characterized. Ionic conductivities and lithium transference number, evaluated by electrochemical techniques after membrane-swelling in organic aprotic solvents (ethylene carbonate-propylene carbonate mixture), display significant values, with sigma approximate to 5 x 10(-4) S cm(-1) at 25 degrees C and t(Li+) close to unity. The absence of solvent leaching on thermal cycles is also noteworthy. The description at molecular level of the lithium transport mechanism has been carefully tackled through a systematic study by Li-7 NMR spectroscopy (pulsed field gradient-PFG and relaxation times), while the mechanical properties of the film electrolytes have been evaluated by dynamic mechanical analysis (DMA) in a wide temperature range. The electrochemical performances of the graphene-based electrolyte in Li/Li symmetric cells and in secondary cells using LiFePO4 as positive electrode show good compatibility and functionality with the Li-metal anode by forming a stable interphase, as well as displaying promising performance in galvanostatic cells.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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