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Non-exponential dis...
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Eng, Mattias P,1977Chalmers tekniska högskola,Chalmers University of Technology
(author)
Non-exponential distance dependence of bridge-mediated electronic coupling
- Article/chapterEnglish2006
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LIBRIS-ID:oai:research.chalmers.se:80c29909-cc7e-49a3-a2aa-8d55246502eb
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https://doi.org/10.1002/anie.200601379DOI
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https://research.chalmers.se/publication/26224URI
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Language:English
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Summary in:English
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Subject category:art swepub-publicationtype
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Donor chromophores attached to oligo-(phenyleneethynylene) molecular bridges of varying length have attenuation factors for electron tunneling β that vary systematically with the donor-bridge (DB) energy gap (see picture). Investigations show that for bridges with ethynylene and vinylene repeating subunits, the electronic coupling increases with increasing donor-acceptor (DA) distance. A simple model accounts for this unexpected observation. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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Albinsson, Bo,1963Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)balb
(author)
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Chalmers tekniska högskola
(creator_code:org_t)
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In:Angewandte Chemie - International Edition: Wiley45:34, s. 5626-56291433-78511521-3773
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