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  • Eng, Mattias P,1977Chalmers tekniska högskola,Chalmers University of Technology (author)

Non-exponential distance dependence of bridge-mediated electronic coupling

  • Article/chapterEnglish2006

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  • Wiley,2006

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  • LIBRIS-ID:oai:research.chalmers.se:80c29909-cc7e-49a3-a2aa-8d55246502eb
  • https://doi.org/10.1002/anie.200601379DOI
  • https://research.chalmers.se/publication/26224URI

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  • Language:English
  • Summary in:English

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  • Subject category:art swepub-publicationtype
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Notes

  • Donor chromophores attached to oligo-(phenyleneethynylene) molecular bridges of varying length have attenuation factors for electron tunneling β that vary systematically with the donor-bridge (DB) energy gap (see picture). Investigations show that for bridges with ethynylene and vinylene repeating subunits, the electronic coupling increases with increasing donor-acceptor (DA) distance. A simple model accounts for this unexpected observation. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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  • Albinsson, Bo,1963Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)balb (author)
  • Chalmers tekniska högskola (creator_code:org_t)

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  • In:Angewandte Chemie - International Edition: Wiley45:34, s. 5626-56291433-78511521-3773

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