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Efficient Oxidative...
Efficient Oxidative Dehydrogenation of Dihydropyrimidinones and Thiocyanation of Aromatic Compounds Using 1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane as the Oxidant
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- Khosravi, Kaveh (author)
- Arak University
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- Azizi, Amir (author)
- Arak University
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- Naserifar, Shirin, 1991 (author)
- Arak University
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(creator_code:org_t)
- 2019
- 2019
- English.
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In: Organic Chemistry Research. ; 2:5, s. 128-138
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Abstract
Subject headings
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- A new, efficient and mild approach for the oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane (THPDPE) as a terminal oxidant was developed. Initially, various substrates bearing different electron-donating and electron-releasing functionalities were synthesized and next under the optimized reaction conditions the desired products were yielded after an easy work-up and the structures were characterized compared with those reported. All of the reactions proceeded in short reaction times and 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane (THPDPE) proved its potential to yield the desired products in high yields.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Thiocyanation
- Dehydropirimidinones
- Oxidative dehydrogenation
- Pyrimidinones
- 2-Tetrahydroperoxy-1
- 2-diphenylethane
Publication and Content Type
- art (subject category)
- ref (subject category)
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