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Review: Periodate o...
Review: Periodate oxidation of wood polysaccharides—Modulation of hierarchies
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- Nypelö, Tiina, 1982 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Berke, Barbara, 1989 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Spirk, Stefan (author)
- Technische Universität Graz
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- Sirviö, Juho Antti (author)
- Oulun Yliopisto,University of Oulu
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(creator_code:org_t)
- Elsevier BV, 2021
- 2021
- English.
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In: Carbohydrate Polymers. - : Elsevier BV. - 0144-8617. ; 252
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Abstract
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- Periodate oxidation of polysaccharides has transitioned from structural analysis into a modification method for engineered materials. This review summarizes the research on this topic. Fibers, fibrils, crystals, and molecules originating from forests that have been subjected to periodate oxidation can be crosslinked with other entities via the generated aldehyde functionality, that can also be oxidized or reduced to carboxyl or alcohol functionality or used as a starting point for further modification. Periodate-oxidized materials can be subjected to thermal transitions that differ from the native cellulose. Oxidation of polysaccharides originating from forests often features oxidation of structures rather than liberated molecules. This leads to changes in macro, micro, and supramolecular assemblies and consequently to alterations in physical properties. This review focuses on these aspects of the modulation of structural hierarchies due to periodate oxidation.
Subject headings
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Polymerteknologi (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Polymer Technologies (hsv//eng)
Keyword
- Cellulose fibrils
- Cellulose nanocrystals
- Periodate oxidation
- Hemicellulose
- Cellulose
- Cellulose fibres
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