Search: onr:"swepub:oai:research.chalmers.se:9e7d9008-e329-4a62-92ba-af1add84dadb" >
Graphitic encapsula...
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Ding, Feng,1970Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU),University of Gothenburg
(author)
Graphitic encapsulation of catalyst particles in carbon nanotube production
- Article/chapterEnglish2006
Publisher, publication year, extent ...
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2006-03-24
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American Chemical Society (ACS),2006
Numbers
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LIBRIS-ID:oai:research.chalmers.se:9e7d9008-e329-4a62-92ba-af1add84dadb
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https://research.chalmers.se/publication/58985URI
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https://doi.org/10.1021/jp055485yDOI
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https://gup.ub.gu.se/publication/58985URI
Supplementary language notes
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Language:English
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Summary in:English
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Classification
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Subject category:art swepub-publicationtype
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Subject category:ref swepub-contenttype
Notes
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A new model is proposed for the encapsulation of catalyst metal particles by graphite layers that are obtained, for example, in low-temperature chemical vapor deposition production of carbon nanotubes (CNTs). In this model graphite layers are primarily formed from the dissolved carbon atoms in the metal-carbide particle when the particle cools. This mechanism is in good agreement with molecular dynamics simulations (which show that precipitated carbon atoms preferentially form graphite sheets instead of CNTs at low temperatures) and experimental results (e.g., encapsulated metal particles are found in low-temperature zones and CNTs in high-temperature regions of production apparatus, very small catalyst particles are generally not encapsulated, and the ratio of the number of graphitic layers to the diameter of the catalyst particle is typically 0.25 nm(-1)).
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Rosen, Arne,1939Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU),University of Gothenburg(Swepub:gu)xrosar
(author)
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Campbell, Eleanor E B,1960Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU),University of Gothenburg(Swepub:gu)xcamel
(author)
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Falk, Lena,1956Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)lklfalk
(author)
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Bolton, Kim,1964Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU),University of Gothenburg(Swepub:gu)xbolki
(author)
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Göteborgs universitetInstitutionen för fysik (GU)
(creator_code:org_t)
Related titles
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In:Journal of Physical Chemistry B: American Chemical Society (ACS)110:15, s. 7666-76701520-52071520-6106
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