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An All-Photonic Molecular Keypad Lock

Andreasson, Joakim, 1973 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Straight, S. D. (author)
Arizona State University
Moore, A. L. (author)
Arizona State University
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Moore, T. A. (author)
Arizona State University
Gust, D. (author)
Arizona State University
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 (creator_code:org_t)
Wiley, 2009
2009
English.
In: Chemistry - A European Journal. - : Wiley. - 1521-3765 .- 0947-6539. ; 15:16, s. 3936-3939
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • An all photonic molecular keypad lock with a reset capacity, that is capable of distinguishing one two-digit code out of eight possible combinations were described. The synthesis and characterization of triad 1 with distilled 2-methyltetrahydrofuran as the solvent for spectroscopic measurement were reported, where the samples were degassed by size freeze-pump-thaw cycles to a final pressure. The functional principle of a keypad lock is that it gives an output signal only when given the correct inputs in the correct order, also the capacity of the triad to perform as a two-input PAND gate with reset capacity are considered. The keypad lock is found to be operated by five optical signals in the UV region including fluorescence emission that signals the actual opening of the lock, which can also be used numerous times without ant photodegradation affecting the performance.

Subject headings

NATURVETENSKAP  -- Kemi -- Fysikalisk kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Physical Chemistry (hsv//eng)
NATURVETENSKAP  -- Kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Keyword

chromophores
molecular devices
logic gates
switches
circuits
photochromism
photochemistry
porphyrinoids
demultiplexer

Publication and Content Type

art (subject category)
ref (subject category)

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