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Sol-gel-derived pot...
Sol-gel-derived potassium-based di-ureasils for "smart windows''
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- Nunes, S. C. (author)
- Universidade de Tras-os-Montes e Alto Douro,University of Trás-os-Montes and Alto Douro
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- Bermudez, V. D. (author)
- Universidade de Tras-os-Montes e Alto Douro,University of Trás-os-Montes and Alto Douro
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- Silva, M. M. (author)
- Universidade do Minho,University of Minho
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- Smith, M. J. (author)
- Universidade do Minho,University of Minho
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- Ostrovskii, Denis, 1967 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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Ferreira, R. A. S. (author)
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Carlos, L. D. (author)
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Rocha, J. (author)
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- Goncalves, A. (author)
- Universidade do Porto,University of Porto
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- Fortunato, E. (author)
- Universidade do Porto,University of Porto
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 2007
- 2007
- English.
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In: Journal of Materials Chemistry. - : Royal Society of Chemistry (RSC). - 1364-5501 .- 0959-9428. ; 17:40, s. 4239-4248
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http://dx.doi.org/10...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Sol-gel-derived KCF3SO3-doped di-urea cross-linked poly(oxyethylene) (POE)/siloxane (di-ureasil) ormolytes with infinity > n >= 1 (n is the number of oxyethylene units per K+ ion) have been analysed. Samples with n. 40 are thermally stable up to 310 degrees C. At n >= 100, POE crystallites are present. At n = 5, a crystalline POE-KCF3SO3 complex with stoichiometry 1 : 1 is formed. In the xerogel with n = 1 this complex coexists with free salt. The highest ionic conductivity is reached at n = 20. The redox stability domain of this material spans 5.0 V. "Free'' anions and weakly coordinated CF3SO3- ions appear to be the main charge carriers at n = 20. The K+ ions interact with the urea carbonyl oxygen atoms at all salt concentrations. Complexation of the cations by POE occurs at n
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Annan teknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Other Engineering and Technologies (hsv//eng)
Keyword
- POLYMER ELECTROLYTES
- ENVIRONMENT
- SALTS
- STATE
- TEMPERATURE
- FILMS
- SPECTRA
- ORMOLYTES
- TRIFLATE
- IONIC-CONDUCTIVITY
Publication and Content Type
- art (subject category)
- ref (subject category)
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- By the author/editor
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Nunes, S. C.
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Bermudez, V. D.
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Silva, M. M.
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Smith, M. J.
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Ostrovskii, Deni ...
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Ferreira, R. A. ...
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show more...
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Carlos, L. D.
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Rocha, J.
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Goncalves, A.
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Fortunato, E.
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show less...
- About the subject
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- ENGINEERING AND TECHNOLOGY
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ENGINEERING AND ...
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and Other Engineerin ...
- Articles in the publication
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Journal of Mater ...
- By the university
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Chalmers University of Technology