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Formic acid electro...
Formic acid electrooxidation catalyzed by Pd/SmOx-C hybrid catalyst in fuel cells
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- Wang, K. Q. (author)
- Changchun Institute of Technology
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Wang, B. (author)
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- Chang, J. F. (author)
- Chinese Academy of Sciences
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- Feng, Ligang, 1983 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Xing, W. (author)
- Chinese Academy of Sciences
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(creator_code:org_t)
- Elsevier BV, 2014
- 2014
- English.
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In: Electrochimica Acta. - : Elsevier BV. - 0013-4686. ; 150, s. 329-336
- Related links:
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http://dx.doi.org/10...
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https://research.cha...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Pd nanoparticles supported on Samarium oxide modified carbon (SmOx/C) hybrid support for the electrooxidation of formic acid is studied. The morphology, composition and electrocatalytic properties are investigated by physical characterization and electrochemical measurements. The results demonstrate that Pd/SmOx-C catalyst has excellent catalytic activity and stability for formic acid oxidation. The current density is about 1.32 times that of the Pd/C catalyst. The electronic effect and oxygen-containing species provided by SmOx accelerate the rate of formic acid electrooxidation. When integrated into the anode of a direct formic acid fuel cell, the maximum power density of 167 mW cm (2) is obtained, which is about 1.4 times that of a commercial Pd/C catalyst.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Fuel cells
- Formic acid electrooxidation
- Pd catalyst
- Tafel slope
Publication and Content Type
- art (subject category)
- ref (subject category)
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