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Asymmetric aerobic ...
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Axelsson, Anton,1991Chalmers tekniska högskola,Chalmers University of Technology
(author)
Asymmetric aerobic oxidative NHC-catalysed synthesis of dihydropyranones utilising a system of electron transfer mediators
- Article/chapterEnglish2016
Publisher, publication year, extent ...
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2016
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electronicrdacarrier
Numbers
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LIBRIS-ID:oai:research.chalmers.se:c1a46855-84a3-412e-be97-bd04e54aea7e
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https://doi.org/10.1039/C6CC06060ADOI
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https://research.chalmers.se/publication/242129URI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:art swepub-publicationtype
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Subject category:ref swepub-contenttype
Notes
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In the context of green chemistry, the replacement of high molecular weight stoichiometric oxidants with O2 is most desirable but difficult. Here, we report the asymmetric aerobic oxidative synthesis of dihydropyranones. The oxidation is aided by a system of electron transfer mediators and is selective toward the homoenolate. The dihydropyranones can be isolated in high to excellent yields, with high ee (up to 95%).
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Hammarvid, Emmelie,1991Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)emmeha
(author)
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Ta, Linda,1989Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)lindat
(author)
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Sundén, Henrik,1978Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)sundenh
(author)
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Chalmers tekniska högskola
(creator_code:org_t)
Related titles
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In:Chemical Communications52:77, s. 11571-115741364-548X1359-7345
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