Search: onr:"swepub:oai:research.chalmers.se:c3c43472-a0c0-4842-8af3-f9ebf46c7cd6" >
Effect of DMSO on t...
Effect of DMSO on the catalytical production of 2,5-bis(hydoxymethyl)furan from 5-hydroxymethylfurfural over Ni/SiO2 catalysts
-
- Ojagh, Houman, 1976 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Achour, Abdenour, 1980 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Ho, Hoang Phuoc, 1983 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
-
show more...
-
- Bernin, Diana, 1979 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Creaser, Derek, 1966 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Pajalic, Oleg (author)
- Perstorp AB
-
- Holmberg, Johan (author)
- Perstorp AB
-
- Olsson, Louise, 1974 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
-
show less...
-
(creator_code:org_t)
- 2022
- 2022
- English.
-
In: Reaction Chemistry and Engineering. - : Royal Society of Chemistry (RSC). - 2058-9883. ; 7:1, s. 192-200
- Related links:
-
https://research.cha... (primary) (free)
-
show more...
-
https://pubs.rsc.org...
-
https://doi.org/10.1...
-
https://research.cha...
-
show less...
Abstract
Subject headings
Close
- Hydroconversion of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydoxymethyl)furan (BHMF) was studied over mono- and bimetallic supported catalysts. It was found that monometallic Ni/SiO2 catalysts exhibited superior performance with a total yield of BHMF of up to 99 wt%. This excellent performance may be attributed to higher Ni dispersion and low acidity of the support. Dimethyl sulfoxide (DMSO) is often present in HMF, due to the route used for its synthesis. DMSO adsorption caused a clear reduction of Ni/SiO2 performance for the HMF hydrodeoxygenation reaction. Characterization of the spent catalysts was performed using HAADF-STEM-EDX, Raman, ICP, and XPS spectroscopies, and showed the presence of sulfur and graphitic carbon, which could explain the deactivation.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
Find in a library
To the university's database
- By the author/editor
-
Ojagh, Houman, 1 ...
-
Achour, Abdenour ...
-
Ho, Hoang Phuoc, ...
-
Bernin, Diana, 1 ...
-
Creaser, Derek, ...
-
Pajalic, Oleg
-
show more...
-
Holmberg, Johan
-
Olsson, Louise, ...
-
show less...
- About the subject
-
- ENGINEERING AND TECHNOLOGY
-
ENGINEERING AND ...
-
and Chemical Enginee ...
-
and Other Chemical E ...
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
-
and Other Chemistry ...
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
-
and Organic Chemistr ...
- Articles in the publication
-
Reaction Chemist ...
- By the university
-
Chalmers University of Technology