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Crumpled Nitrogen-D...
Crumpled Nitrogen-Doped Graphene-Wrapped Phosphorus Composite as a Promising Anode for Lithium-Ion Batteries
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- Jiao, Xingxing (author)
- Xi'an Jiaotong University
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- Liu, Yangyang (author)
- Xi'an Jiaotong University
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- Li, Tongtong (author)
- Xi'an Jiaotong University
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- Zhang, Chaofan (author)
- Xi'an Jiaotong University
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- Xu, Xieyu (author)
- Xi'an Jiaotong University
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- Kapitanova, Olesya O. (author)
- M. V. Lomonosov Moscow State University
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- He, Cheng (author)
- Xi'an Jiaotong University
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- Li, Bing (author)
- Xi'an Jiaotong University
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- Xiong, Shizhao, 1985 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Song, Jiangxuan (author)
- Xi'an Jiaotong University
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Xi'an Jiaotong University M V. Lomonosov Moscow State University (creator_code:org_t)
- 2019-08-02
- 2019
- English.
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In: ACS Applied Materials & Interfaces. - : American Chemical Society (ACS). - 1944-8252 .- 1944-8244. ; 11:34, s. 30858-30864
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Abstract
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- Red phosphorus (P) has recently gained wide attention because of the high theoretical capacity of 2596 mA h/g, which has been regarded as promising anode material for lithium-ion batteries (LIBs). However, the actual application of red P in LIBs is hampered by the huge expansion of volume and low electronic conductivity. Herein, we design a kind of red phosphorus/crumpled nitrogen-doped graphene (P/CNG) nanocomposites with high capacity density and great rate performance as anode material for LIBs. This anode material was rationally fabricated through the scalable ball-milling method. The nanocomposite structure of P/CNG improves the electron conductivity and alleviates volume change of raw red P because of the three-dimension (3D) framework, massive defects and active sites of CNG sheets. As expected, the P/CNG composite shows excellent electrochemical performances, including high capacity (2522.6 mA h/g at 130 mA/g), remarkable rate capability (1340.5 mA h/g at 3900 mA/g), and great cyclability (1470.1 mA h/g at 1300 mA/g for 300 cycles). This work may provide a broad prospect for a great rate performance of P-based anode material for LIBs.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Polymerteknologi (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Polymer Technologies (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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- By the author/editor
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Jiao, Xingxing
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Liu, Yangyang
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Li, Tongtong
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Zhang, Chaofan
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Xu, Xieyu
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Kapitanova, Oles ...
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show more...
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He, Cheng
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Li, Bing
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Xiong, Shizhao, ...
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Song, Jiangxuan
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Physical Chemist ...
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- ENGINEERING AND TECHNOLOGY
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ENGINEERING AND ...
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and Chemical Enginee ...
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and Polymer Technolo ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Condensed Matter ...
- Articles in the publication
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ACS Applied Mate ...
- By the university
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Chalmers University of Technology